Lutetium Oxide Properties |
Synonym | Lutetium oxide, Lutetium sesquioxide |
CASNo. | 12032-20-1 |
Chemical formula | Lu2O3 |
Molar mass | 397.932g/mol |
Melting point | 2,490°C(4,510°F;2,760K) |
Boiling point | 3,980°C(7,200°F;4,250K) |
Solubility in other solvents | Insoluble |
Band gap | 5.5eV |
High Purity Lutetium Oxide Specification
ParticleSize(D50) | 2.85 μm |
Purity(Lu2O3) | ≧99.999% |
TREO(TotalRareEarthOxides) | 99.55% |
RE Impurities Contents | ppm | Non-REEs Impurities | ppm |
La2O3 | <1 | Fe2O3 | 1.39 |
CeO2 | <1 | SiO2 | 10.75 |
Pr6O11 | <1 | CaO | 23.49 |
Nd2O3 | <1 | PbO | Nd |
Sm2O3 | <1 | CL¯ | 86.64 |
Eu2O3 | <1 | L.O.I | 0.15% |
Gd2O3 | <1 | ||
Tb4O7 | <1 | ||
Dy2O3 | <1 | ||
Ho2O3 | <1 | ||
Er2O3 | <1 | ||
Tm2O3 | <1 | ||
Yb2O3 | <1 | ||
Y2O3 | <1 |
【Packaging】25KG/bag Requirements:moisture proof, dust-free, dry, ventilate and clean.
What is Lutetium Oxide used for?
Laser crystals and core matrix materials for solid-state lasers:
Core applications: Lu₂O₃ is a key starting material for manufacturing high-performance laser crystals such as lutetium-doped yttrium aluminum garnet and lutetium-doped yttrium lithium fluoride. These crystals are usually expressed as Lu: YAG (Yttrium Aluminum Garnet) or Lu: YLF (Yttrium Lithium Fluoride).
Mechanism of action: Lutetium ions (Lu³⁺) themselves are usually not used as active ions (laser emission centers). Still, as part of the matrix lattice, they can provide an extremely stable and compact lattice environment. When doped with other rare earth ions (such as Nd³⁺, Yb³⁺, Er³⁺, Tm³⁺, Ho³⁺), Lu₂O₃-based crystals exhibit:
High thermal conductivity: Effectively dissipates heat, allowing high-power laser operation and reducing thermal lens effects.
High chemical and mechanical stability: Ensure long-term reliability of lasers in harsh environments.
Excellent phonon energy properties: Affects the energy level lifetime and quantum efficiency of laser ions.
Applications: These lasers are widely used in industrial material processing (cutting, welding, marking), medical (ophthalmic surgery, skin treatment), scientific research, lidar, and potential inertial confinement fusion research.
Special ceramics and glass:
High refractive index/low dispersion optical glass: Lu₂O₃ is used to make special optical glass (such as lanthanide optical glass) with extremely high refractive index and extremely low dispersion characteristics. This glass is essential for correcting chromatic aberration in advanced optical systems (such as microscope objectives, high-end camera lenses, and lithography systems).
Transparent ceramics: Lu₂O₃ itself or in combination with other oxides (such as Y₂O₃) can be used to make transparent polycrystalline ceramics. These ceramics have optical uniformity and light transmittance similar to single crystals, but are larger in size, higher in mechanical strength, and may be less expensive to prepare. Applications include laser gain media, infrared windows, missile fairings, and high-intensity lighting lampshades.
Structural ceramic additives: A small amount of Lu₂O₃ can be added as a sintering aid or grain boundary engineering agent to improve the high-temperature mechanical properties, oxidation resistance, and creep resistance of other advanced ceramics (such as silicon nitride and silicon carbide), and is used in high-temperature bearings, cutting tools, and turbine engine components.
Scintillator and radiation detection:
Core raw materials: Lu₂O₃ is an indispensable raw material for synthesizing high-performance lutetium-based scintillator single crystals and ceramics. The most important representatives are:
Lutetium silicate: Lu₂SiO₅:Ce³⁺ and its derivative crystals. With high density (~7.4 g/cm³), high effective atomic number, fast decay time, and high light output, it is the most advanced detector material in positron emission tomography.
Lutetium yttrium aluminate: (Lu, Y) )₃Al₅O₁₂:Ce³⁺ ceramics. Combining the advantages of high light output, fast decay, good energy resolution, and ceramics that can be made into large sizes and complex shapes, it is widely used in medical imaging (PET/CT), high-energy physics experiments, homeland security (baggage/cargo scanning), and oil well logging.
Advantages: The high atomic number (71) of lutetium gives the material excellent high-energy photon (X-ray, gamma ray) blocking ability, improving detection efficiency.
Phosphors and luminescent materials:
Matrix materials: Lu₂O₃ can be used as an efficient matrix for rare-earth ion-activated luminescent materials. When doped with europium ions (Eu³⁺), it can emit very pure red fluorescence (main peak ~611 nm) with a narrow emission bandwidth and high color purity.
Applications: Mainly used in high-end display technology (such as medical high-resolution X-ray image intensification screens, certain types of field emission displays) and fluorescent probes (biomarkers, sensors). Its excellent chemical and thermal stability ensures the long life of the phosphor.
Catalytic effect:
Catalyst component: Lu₂O₃ is active in a variety of catalytic reactions due to its Lewis acidity:
Petroleum refining: It can be used as a catalyst carrier or active component (sometimes used in combination with other metal oxides) in processes such as cracking (decomposing heavy oil into light fuels), alkylation (producing high-octane gasoline components), and hydroprocessing (desulfurization, denitrogenation).
Polymerization reaction: In the polymerization reaction of olefins (such as ethylene and propylene), Lu₂O₃ or its derivatives can be used as catalyst components to affect the molecular weight distribution and microstructure of the polymer.
Methane conversion: It shows research value in reactions such as methane oxidative coupling or reforming to produce synthesis gas.
Automobile exhaust treatment: It is used as a stabilizer or co-catalyst component in three-way catalysts (although its application is less than that of cerium, zirconium, etc.).
Mechanism: Its catalytic activity mainly comes from the adsorption and activation ability of surface oxygen vacancies and exposed Lu³⁺ ion sites on reactant molecules.
Other cutting-edge applications:
Nuclear industry: The isotope Lu-176 (natural abundance of about 2.6%) has a large thermal neutron capture cross section and can be converted into the medically valuable radioactive isotope Lu-177 (for targeted radiotherapy) after neutron irradiation. Lu₂O₃ is the starting material for purifying Lu-176 or preparing Lu-177 radiopharmaceuticals. High-purity Lu₂O₃ can also be used in the research of neutron-absorbing materials or nuclear control rods.
Electronic materials: As a research object of high-κ gate dielectric materials (used to replace silicon dioxide in silicon-based chips), or for the research of ferroelectric and multiferroic materials.
Coating materials: Used to prepare protective coatings that are resistant to high temperatures, corrosion, or have special optical properties (such as for aircraft engines or satellite optical components).
Experimental physics: Used as a Cherenkov radiator material in particle physics experiments.
Summary:
Lutetium oxide (Lu₂O₃) is by no means an ordinary raw material. It is a key strategic material supporting modern cutting-edge technology. Its core value lies in:
As a top-level matrix material for high-performance laser crystals (such as Lu: YAG, Lu: YLF), it enables high-power, high-stability solid-state lasers.
As the cornerstone of the next generation of scintillator materials (LSO, LYSO, LuAG: Ce), it drives the innovation of medical imaging (PET/CT) and radiation detection technology.
It gives special optical glass and transparent ceramics excellent optical properties (high refraction, low dispersion, wide light transmission range).
As a high-efficiency phosphor matrix (Lu₂O₃:Eu³⁺), it provides high-purity red light emission.
It exhibits a unique reaction activation ability in heterogeneous catalysis.
All of these applications rely on the high purity of Lu₂O₃ (usually requiring 4N/99.99% or even 5N/99.999% or more), precise stoichiometric ratio, and specific physical form (such as ultrafine powder, nanoparticles). The depth and breadth of its application in high-tech fields are still expanding, especially in the fields of laser technology, medical imaging, and nuclear medicine, where it has an irreplaceable position.