Samarium(III) OxideProperties
CAS No.: | 12060-58-1 | |
Chemical formula | Sm2O3 | |
Molar mass | 348.72 g/mol | |
Appearance | yellow-white crystals | |
Density | 8.347 g/cm3 | |
Melting point | 2,335 °C (4,235 °F; 2,608 K) | |
Boiling point | Not Stated | |
Solubility in water | insoluble |
High Purity Samarium(III) Oxide Specification
Particle Size(D50) 3.67 μm
Purity((Sm2O3) | 99.9% |
TREO(Total Rare Earth Oxides) | 99.34% |
RE Impurities Contents | ppm | Non-REEs Impurities | ppm |
La2O3 | 72 | Fe2O3 | 9.42 |
CeO2 | 73 | SiO2 | 29.58 |
Pr6O11 | 76 | CaO | 1421.88 |
Nd2O3 | 633 | CL¯ | 42.64 |
Eu2O3 | 22 | L.O.I | 0.79% |
Gd2O3 | <10 | ||
Tb4O7 | <10 | ||
Dy2O3 | <10 | ||
Ho2O3 | <10 | ||
Er2O3 | <10 | ||
Tm2O3 | <10 | ||
Yb2O3 | <10 | ||
Lu2O3 | <10 | ||
Y2O3 | <10 |
Packaging】25KG/bag Requirements:moisture proof, dust-free, dry, ventilate and clean.
What is Samarium(III) Oxide used for?
Applications of Samarium(III) Oxide (Sm₂O₃) Powder**
Samarium(III) Oxide (Sm₂O₃) is a versatile rare-earth compound prized for its neutron absorption, catalytic activity, and optical properties. Its thermal stability, chemical inertness, and unique interaction with radiation make it critical across nuclear, optical, and chemical industries. Below are its key uses:
1. Nuclear Energy & Radiation Control
Neutron Absorption:
Nuclear Reactor Control Rods: Sm₂O₃ is a primary component in control rods for thermal neutron absorption, ensuring safe and stable nuclear fission reactions in power plants and research reactors.
Radiation Shielding: Incorporated into composite materials for shielding against neutron radiation in medical and industrial equipment.
2. Optical & Infrared Technologies
Infrared-Absorbing Glass:
- Used in specialty optical glass (e.g., laser goggles, night-vision devices) to block infrared radiation while maintaining visible light transparency.
- Enhances performance in military targeting systems, spacecraft windows, and high-power laser applications.
Phosphor Additives:
- Doped into glass and ceramics to modify luminescence properties for LEDs, display panels, and X-ray intensifying screens.
3. Catalysis & Chemical Synthesis
Dehydration & Dehydrogenation Reactions:
- Catalyzes the conversion of primary and secondary alcohols into alkenes or ketones, critical in organic synthesis for pharmaceuticals, fragrances, and polymers.
- Outperforms conventional catalysts in selectivity and stability under high-temperature conditions.
Hydrocarbon Processing:
- Facilitates cracking and reforming reactions in petrochemical refining to optimize fuel production.
4. Advanced Materials & Electronics
Samarium Compound Synthesis:
- Serves as a precursor for producing samarium salts (e.g., SmCl₃, Sm(NO₃)₃) used in magnetic materials, catalysts, and phosphors.
Solid-State Devices:
- Incorporated into solid oxide fuel cells (SOFCs) and gas sensors to enhance ionic conductivity and durability.
Magnetic Materials:
- Key ingredient in samarium-cobalt (SmCo) magnets for high-temperature aerospace motors, precision actuators, and MRI systems.
5. Emerging & Niche Applications
Quantum Computing:
- Investigated for use in quantum memory devices due to its unique electron configuration.
Environmental Remediation:
- Applied in photocatalytic systems for degrading organic pollutants under UV/visible light.
Thermoelectric Materials**:
- Explored in high-efficiency thermoelectric generators for waste heat recovery.
Key Advantages of Sm₂O₃
High Neutron Capture Cross-Section: Ensures efficient neutron absorption for nuclear safety.
Thermal Stability: Maintains structural integrity up to **2,300°C**, ideal for extreme environments.
Chemical Versatility: Compatible with aqueous and non-aqueous synthesis routes.
Industry-Specific Benefits
Energy: Enhances reactor safety and efficiency in nuclear power generation.
Defense & Aerospace: Enables lightweight radiation shielding and high-performance optical systems.
Electronics: Drives innovation in miniaturized magnetic and thermoelectric devices.
Samarium(III) Oxide is a cornerstone of advanced technology, bridging nuclear safety, optical innovation, and sustainable chemistry. Its role in enabling cutting-edge solutions across energy, defense, and materials science underscores its irreplaceable value in modern industry.
Note: Sm₂O₃’s low toxicity and environmental stability align with green chemistry initiatives, supporting its use in eco-friendly catalytic processes.