Lanthanum Hexaboride
Synonym | Lanthanum Boride |
CASNo. | 12008-21-8 |
Chemical formula | LaB6 |
Molar mass | 203.78g/mol |
Appearance | intense purple violet |
Density | 4.72g/cm3 |
Melting point | 2,210°C(4,010°F;2,480K) |
Solubility in water | insoluble |
High Purity Lanthanum Hexaboride Specification |
50nm 100nm 500nm 1μm 5μm 8μm1 2μm 18μm 25μm |
What is Lanthanum Hexaboride (LaB₆) used for? Applications of Lanthanum Hexaboride (LaB₆) Lanthanum Hexaboride (LaB₆), a rare-earth boride compound, is renowned for its exceptional electron emission properties, thermal stability, and chemical resistance. Its unique combination of high melting point (~2,710°C), low work function, and durability makes it indispensable in advanced electronics, analytical instrumentation, and cutting-edge technologies. Below are its key uses:
1. High-Performance Electron Emission Systems Electron Beam Sources: Superior Cathode Material: Replaces traditional tungsten cathodes in high-power electron emission systems due to its lower work function** (2.4–2.8 eV) and higher current density, ensuring brighter, more stable electron beams. Critical Applications: Electron Microscopes: Enhances resolution and longevity in scanning electron microscopes (SEMs) and transmission electron microscopes (TEMs). Electron Beam Lithography: Enables ultra-precise nanofabrication for semiconductor and photonic devices. Free Electron Lasers (FELs): Powers high-energy electron beams for scientific research and medical imaging. Microwave & Vacuum Tubes: Used in magnetrons, klystrons, and traveling-wave tubes (TWTs) for radar systems, satellite communications, and defense technologies.
2. Advanced Manufacturing & Materials Science Electron Beam Welding & Heating: Provides highly focused heat sources for precision welding, additive manufacturing, and surface treatment in aerospace and automotive industries. Coatings & Thin Films: Applied as protective coatings on turbine blades, rocket nozzles, and nuclear reactor components to resist extreme temperatures and oxidation. Single-Crystal LaB₆: Serves as a premium cathode material in particle accelerators, synchrotrons, and ion implantation systems.
3. Analytical Instrumentation X-Ray Diffraction (XRD) Standards: Acts as a certified size/strain reference material to calibrate instrumental broadening in XRD analysis, ensuring accuracy in crystallographic studies. X-Ray Tubes: Enhances brightness and efficiency in medical and industrial X-ray sources.
4. Emerging & Niche Technologies Quantum Computing & Research: Investigated for use in quantum emitters and spintronic devices due to its low electron scattering and high carrier mobility. Plasma Display Panels (PDPs): Improves efficiency and lifespan in high-definition displays. Space Exploration: Utilized in ion thrusters and spacecraft sensors for deep-space missions.
5. Industrial & Environmental Applications High-Temperature Sensors: Functions in thermocouples and thermal probes for metallurgical processes and molten metal monitoring. Superconducting Materials: Explored in superconducting composites for energy storage and magnetic levitation systems.
Key Advantages of LaB₆ Ultra-High Thermal Stability: Maintains performance in extreme environments (up to 1,800°C in vacuum). Chemical Inertness: Resists corrosion from acids, alkalis, and reactive gases. Longevity: Outperforms tungsten cathodes by 10–20x in operational lifespan.
Industry-Specific Benefits Aerospace & Defense: Reliable radar systems, satellite communications, and thermal protection coatings. Semiconductors: Enables next-generation lithography for sub-5nm chip fabrication. Research & Healthcare: High-resolution imaging in TEMs and advanced X-ray diagnostics.
Lanthanum Hexaboride is a cornerstone of modern high-tech industries, driving innovation in nanotechnology, energy, and quantum sciences. Its unparalleled electron emission capabilities and robustness solidify its role as a critical material for both current and next-generation technologies.
Note: LaB₆ nanoparticles are increasingly used in field-emission displays (FEDs) and nanoelectronics, highlighting its adaptability to evolving technological demands.
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